EBOOK - The Metallurgy of Zinc Coated Steels 1st Edition (Arnold Marder & Frank Goodwin) Full



The Metallurgy of Zinc Coated Steels provides a comprehensive overview of the science and engineering of zinc coatings. Beginning with a look at new innovations made in the hot-dip coating methods (CGL), the book goes on to discuss phase equilibria, Zn bath phenomena and overlay coating formations. Both processing methods and controls are covered, as well as corrosion resistance and coating product properties. The book concludes with a discussion of future opportunities for zinc coatings. This book is a vital resource for both individuals new to this area while also serving as a handbook for users and producers of zinc coatings.



Introduction

Reference

Chapter 1: History of zinc-coated steel

Abstract

1.1: Zinc

1.2: In the beginning

1.3: Zinc coating processing

1.4: Zinc coating alloy development

A: Appendix

References

Chapter 2: Hot-dip coating methods: Continuous processing (CGL)

Abstract

2.1: History and overview

2.2: Cleaning

2.3: Steel types for continuous galvanizing

2.4: Galvanizing pretreatment steps for AHSS

2.5: Overaging in the CGL

2.6: Metallic coating pretreatments

2.7: Galvanizing of hot rolled strip

2.8: Furnace temperature control

2.9: CGL rapid cooling section developments

2.10: Strip entry snout control

2.11: Alloy coating developments

2.12: Zinc coating wetting behavior during galvanizing

2.13: Phase transformations after zinc coating

2.14: Coating solidification developments

2.15: Temper rolling and tension leveling

2.16: Passivation and lubrication treatments

2.17: Improvements in inspection practice

References

Chapter 3: Zn coating phase equilibria

Abstract

3.1: The formation of a Zn coating

3.2: Zn-based coating systems

3.3: Equilibrium phase diagrams

References

Chapter 4: Zinc bath phenomena

Abstract

4.1: Introduction

4.2: Typical continuous galvanizing bath characteristics

4.3: Fluid flow and temperature patterns in the galvanizing bath

4.4: Bath chemistry

4.5: Effect of bath geometry and operating variables on dross production

4.6: Dross precipitation and dissolution

4.7: Bath management during transitions between galvanneal and galvanize (GA → GI), galvanize and galvanneal (GI → GA)

4.8: Entry snout phenomena and control of coating quality

4.9: Galvanizing bath top skimmings and bottom dross removal

4.10: The metallurgy of galvanizing bath hardware

4.11: Production of exposed quality GI

4.12: Summary of effects of bath Al composition

References

Further reading

Chapter 5: Interface reactions

Abstract

5.1: Introduction

5.2: The hot-dip process review

5.3: Interface reactions

5.4: Wettability

5.5: Interface response

5.6: Composition effects on interface reactions

5.7: Kinetics of the interfacial reaction

5.8: Summary

References

Chapter 6: Overlay coating formation

Abstract

6.1: Introduction

6.2: Phase equilibria

6.3: Galvanized (GI) coatings (< 1 wt% Al)

6.4: Coatings with Al (5–55 wt% Al)

6.5: Coatings with Al and Mg

6.6: Substrate alloy additions

References

Chapter 7: Hot-dip galvanized coating weight control

Abstract

7.1: Introduction

7.2: Liquid metal properties affecting coating control

7.3: History of development of coating controls

7.4: Development of process models and operation correlations: Steady-state models

7.5: Gas knife designs affecting coating control

7.6: Factors affecting coating weight variability

7.7: Splashing and the limit to line speed

7.8: Production of thick coating weights on heavy gauge cold and hot rolled steels

7.9: Strip roughness effects

7.10: Coating weight measurement and online control

7.11: Nitrogen gas wiping

7.12: Other technical considerations

7.13: Coating weight standards

A: Appendix

References

Chapter 8: Galvannealing

Abstract

8.1: Introduction—History

8.2: Galvanneal processing

8.3: Phase equilibria

8.4: Diffusion

8.5: Kinetics

8.6: Galvanneal microstructure

8.7: Substrate steel chemistry

References

Chapter 9: Electrogalvanizing processes (EG coatings)

Abstract

9.1: Introduction

9.2: Processing methods

9.3: Zn-M coatings and phase formation

9.4: Electrodeposited nanocrystalline Zn coatings

9.5: Summary of ED processing

References

Chapter 10: Physical vapor deposited coatings

Abstract

10.1: Introduction

10.2: PVD properties of zinc

10.3: PVD process basics

10.4: Electron beam vaporization and deposition

10.5: Jet vapor deposition (JVD)

10.6: Performance of vapor deposited coated steels

10.7: Summary

References

Chapter 11: Corrosion behavior

Abstract

11.1: Introduction

11.2: The nature of the surface of zinc and zinc alloy coated sheet steel and initial reactions with the environment

11.3: Corrosion mechanisms and coating microstructure

11.4: Galvanic corrosion and cut edge protection

11.5: Corrosion behavior in atmospheric exposures

11.6: Corrosion in automobile environments

11.7: Corrosion of galvanized press-hardened steels

11.8: Corrosion and hydrogen uptake in the steel

11.9: White rust (storage stain)

References

Chapter 12: Zn-coated steel product properties

Abstract

12.1: Corrosion performance of painted Zn and Zn alloy coated sheet

12.2: Formability of zinc-coated sheet steels

12.3: Joining zinc-coated steels

References

Chapter 13: Zn-coated high-strength steel

Abstract

13.1: High-temperature Zn-coated steel processing

13.2: Zn coating formation

13.3: Hot press forming of Zn-coated steel

References

Chapter 14: Defect identification and remediation in zinc coated steel sheet

Abstract

14.1: Introduction

14.2: Defects related to strip processing

14.3: Defects relating to chemical cleaning

14.4: Defects related to annealing furnace

14.5: Defects related to the snout, zinc bath condition, and bath hardware

14.6: Wiping related defects

14.7: Temper mill related defects

14.8: Galvanneal-specific defects

14.9: Delivery end and other defects

14.10: Defect modeling and control

14.11: Effect of automotive paint systems on zinc coating appearance

References

Chapter 15: General galvanizing

Abstract

15.1: Introduction

15.2: General galvanizing pretreatment steps

15.3: Hot-dip coating with zinc and zinc alloys

15.4: Hydrogen effects in general galvanized articles

15.5: Management of general galvanizing baths

References

Further reading

Chapter 16: New opportunities

Abstract

16.1: Introduction

16.2: Environmental performance

16.3: Process integration and quality assurance—“Industry 4.0”

16.4: Emerging generations of Zn-coated steels

16.5: Extending capabilities of existing coating processes

16.6: New coating processes

16.7: New performance capabilities for zinc-coated steel

References

Index



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The Metallurgy of Zinc Coated Steels provides a comprehensive overview of the science and engineering of zinc coatings. Beginning with a look at new innovations made in the hot-dip coating methods (CGL), the book goes on to discuss phase equilibria, Zn bath phenomena and overlay coating formations. Both processing methods and controls are covered, as well as corrosion resistance and coating product properties. The book concludes with a discussion of future opportunities for zinc coatings. This book is a vital resource for both individuals new to this area while also serving as a handbook for users and producers of zinc coatings.



Introduction

Reference

Chapter 1: History of zinc-coated steel

Abstract

1.1: Zinc

1.2: In the beginning

1.3: Zinc coating processing

1.4: Zinc coating alloy development

A: Appendix

References

Chapter 2: Hot-dip coating methods: Continuous processing (CGL)

Abstract

2.1: History and overview

2.2: Cleaning

2.3: Steel types for continuous galvanizing

2.4: Galvanizing pretreatment steps for AHSS

2.5: Overaging in the CGL

2.6: Metallic coating pretreatments

2.7: Galvanizing of hot rolled strip

2.8: Furnace temperature control

2.9: CGL rapid cooling section developments

2.10: Strip entry snout control

2.11: Alloy coating developments

2.12: Zinc coating wetting behavior during galvanizing

2.13: Phase transformations after zinc coating

2.14: Coating solidification developments

2.15: Temper rolling and tension leveling

2.16: Passivation and lubrication treatments

2.17: Improvements in inspection practice

References

Chapter 3: Zn coating phase equilibria

Abstract

3.1: The formation of a Zn coating

3.2: Zn-based coating systems

3.3: Equilibrium phase diagrams

References

Chapter 4: Zinc bath phenomena

Abstract

4.1: Introduction

4.2: Typical continuous galvanizing bath characteristics

4.3: Fluid flow and temperature patterns in the galvanizing bath

4.4: Bath chemistry

4.5: Effect of bath geometry and operating variables on dross production

4.6: Dross precipitation and dissolution

4.7: Bath management during transitions between galvanneal and galvanize (GA → GI), galvanize and galvanneal (GI → GA)

4.8: Entry snout phenomena and control of coating quality

4.9: Galvanizing bath top skimmings and bottom dross removal

4.10: The metallurgy of galvanizing bath hardware

4.11: Production of exposed quality GI

4.12: Summary of effects of bath Al composition

References

Further reading

Chapter 5: Interface reactions

Abstract

5.1: Introduction

5.2: The hot-dip process review

5.3: Interface reactions

5.4: Wettability

5.5: Interface response

5.6: Composition effects on interface reactions

5.7: Kinetics of the interfacial reaction

5.8: Summary

References

Chapter 6: Overlay coating formation

Abstract

6.1: Introduction

6.2: Phase equilibria

6.3: Galvanized (GI) coatings (< 1 wt% Al)

6.4: Coatings with Al (5–55 wt% Al)

6.5: Coatings with Al and Mg

6.6: Substrate alloy additions

References

Chapter 7: Hot-dip galvanized coating weight control

Abstract

7.1: Introduction

7.2: Liquid metal properties affecting coating control

7.3: History of development of coating controls

7.4: Development of process models and operation correlations: Steady-state models

7.5: Gas knife designs affecting coating control

7.6: Factors affecting coating weight variability

7.7: Splashing and the limit to line speed

7.8: Production of thick coating weights on heavy gauge cold and hot rolled steels

7.9: Strip roughness effects

7.10: Coating weight measurement and online control

7.11: Nitrogen gas wiping

7.12: Other technical considerations

7.13: Coating weight standards

A: Appendix

References

Chapter 8: Galvannealing

Abstract

8.1: Introduction—History

8.2: Galvanneal processing

8.3: Phase equilibria

8.4: Diffusion

8.5: Kinetics

8.6: Galvanneal microstructure

8.7: Substrate steel chemistry

References

Chapter 9: Electrogalvanizing processes (EG coatings)

Abstract

9.1: Introduction

9.2: Processing methods

9.3: Zn-M coatings and phase formation

9.4: Electrodeposited nanocrystalline Zn coatings

9.5: Summary of ED processing

References

Chapter 10: Physical vapor deposited coatings

Abstract

10.1: Introduction

10.2: PVD properties of zinc

10.3: PVD process basics

10.4: Electron beam vaporization and deposition

10.5: Jet vapor deposition (JVD)

10.6: Performance of vapor deposited coated steels

10.7: Summary

References

Chapter 11: Corrosion behavior

Abstract

11.1: Introduction

11.2: The nature of the surface of zinc and zinc alloy coated sheet steel and initial reactions with the environment

11.3: Corrosion mechanisms and coating microstructure

11.4: Galvanic corrosion and cut edge protection

11.5: Corrosion behavior in atmospheric exposures

11.6: Corrosion in automobile environments

11.7: Corrosion of galvanized press-hardened steels

11.8: Corrosion and hydrogen uptake in the steel

11.9: White rust (storage stain)

References

Chapter 12: Zn-coated steel product properties

Abstract

12.1: Corrosion performance of painted Zn and Zn alloy coated sheet

12.2: Formability of zinc-coated sheet steels

12.3: Joining zinc-coated steels

References

Chapter 13: Zn-coated high-strength steel

Abstract

13.1: High-temperature Zn-coated steel processing

13.2: Zn coating formation

13.3: Hot press forming of Zn-coated steel

References

Chapter 14: Defect identification and remediation in zinc coated steel sheet

Abstract

14.1: Introduction

14.2: Defects related to strip processing

14.3: Defects relating to chemical cleaning

14.4: Defects related to annealing furnace

14.5: Defects related to the snout, zinc bath condition, and bath hardware

14.6: Wiping related defects

14.7: Temper mill related defects

14.8: Galvanneal-specific defects

14.9: Delivery end and other defects

14.10: Defect modeling and control

14.11: Effect of automotive paint systems on zinc coating appearance

References

Chapter 15: General galvanizing

Abstract

15.1: Introduction

15.2: General galvanizing pretreatment steps

15.3: Hot-dip coating with zinc and zinc alloys

15.4: Hydrogen effects in general galvanized articles

15.5: Management of general galvanizing baths

References

Further reading

Chapter 16: New opportunities

Abstract

16.1: Introduction

16.2: Environmental performance

16.3: Process integration and quality assurance—“Industry 4.0”

16.4: Emerging generations of Zn-coated steels

16.5: Extending capabilities of existing coating processes

16.6: New coating processes

16.7: New performance capabilities for zinc-coated steel

References

Index



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